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In general, kinetic enolates are favored by cold temperatures, ailments that provide fairly ionic steel–oxygen bonding, and swift deprotonation using a slight extra of a robust, sterically hindered foundation. The large base only deprotonates the more obtainable hydrogen, and the reduced temperatures and surplus foundation help steer clear of equilibration to the greater secure alternate enolate after Preliminary enolate development. Thermodynamic enolates are favored by longer equilibration periods at larger temperatures, ailments that provide relatively covalent metal–oxygen bonding, and use of a slight sub-stoichiometric level of sturdy foundation.
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The response between an aldehyde/ketone and an aromatic carbonyl compound lacking an alpha-hydrogen (cross aldol condensation) is known as the Claisen-Schmidt condensation. This response is named after two of its pioneering investigators Rainer Ludwig Claisen and J.
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The challenge of "Handle" from the aldol addition is most effective demonstrated by an case in point. Consider the outcome of the hypothetical reaction:
It is crucial to distinguish the aldol condensation from other addition reactions of carbonyl compounds.